Carbonyl detective: aldehyde or ketone?

1. Your mystery compound

2. Run tests (as few as you need)

3. Your verdict

What each test detects

TestPositive whenSign
Tollens' ([Ag(NH₃)₂]⁺)the compound is an aldehyde (H on the C=O carbon)silver mirror
Fehling's (Cu²⁺, blue)the compound is an aliphatic aldehydebrick-red Cu₂O
Iodoform (I₂ / NaOH)the compound has a CH₃CO– group (methyl ketones, ethanal)yellow CHI₃

Results follow these general rules under ordinary test conditions. Some special compounds, such as α-hydroxy ketones, can also reduce Tollens' and Fehling's reagents.