01The question
Q.5 Consider a hydrogen atom with vk, rk, and Kk denoting the velocity, orbital radius and kinetic energy of the electron in the kth orbit, respectively. The electron undergoes a transition from the nth orbit, emitting radiation corresponding to the Lyman series. Considering h to be the Planck’s constant and ϵ0 the permittivity of the free space, the correct statement(s) is/are:
- (A)Magnitude of change in kinetic energy of electron can be expressed as h/4π · |n vn/rn − v1/r1|.
- (B)Magnitude of change in de Broglie wavelength of the electron can be expressed as e²/4ϵ0 · |1/Kn − 1/K1|.
- (C)Frequency of the radiation emitted can be expressed as e²/(8πϵ0h) · (1/r1 − 1/rn).
- (D)Magnitude of change in total energy of the electron can be expressed as h/2π · |v1/r1 − n vn/rn|.
02The experiment
Answer—
Press START: the electron jumps, and each expression is checked against the measured change.
Ready.
From orbit n
Speed
Wave
03Detailed solution
Answer: —
- Bohr's rule links everything. In orbit k: m vk rk = k h/2π. The Coulomb force supplies the centripetal force: m vk²/rk = e²/(4πϵ0rk²).
Kk = ½m vk² = ½(m vk rk)(vk/rk) = (h/4π) · k vk/rk and Kk = e²/(8πϵ0rk).
- (A) is true. |ΔK| = |Kn − K1| = (h/4π)|n vn/rn − v1/r1|.
- (D) is false. The total energy is Ek = −Kk, so |ΔE| = |ΔK| = (h/4π)|…|. The expression in (D) has h/2π and is twice the true change.
- (C) is true. The photon carries away hν = En − E1 = K1 − Kn = (e²/8πϵ0)(1/r1 − 1/rn).
ν = e²/(8πϵ0h) · (1/r1 − 1/rn).
- (B) is false. λk = h/(m vk) = 2πrk/k. This is the standing wave the experiment draws: k wavelengths fit around orbit k. With rk = e²/(8πϵ0Kk):
λk = e²/(4ϵ0 k Kk) ⇒ |Δλ| = (e²/4ϵ0)|1/(n Kn) − 1/K1|.Option (B) drops the 1/n, so it is wrong for every Lyman line (n ≥ 2). For n = 3 it gives 26.6 Å instead of the true 6.65 Å.
| Jump 3 → 1 | Measured change | Expression in the option | Verdict |
|---|---|---|---|
| (A) |ΔK| | 12.09 eV | 12.09 eV | True |
| (B) |Δλ| | 6.65 Å | 26.6 Å | False (missing 1/n) |
| (C) ν | 2.92 × 1015 Hz | 2.92 × 1015 Hz | True |
| (D) |ΔE| | 12.09 eV | 24.19 eV | False (twice the change) |
Understand the concept
In the Bohr model one rule, m v r = kħ, fixes the whole orbit. The speed falls as 1/k, the radius grows as k², the kinetic energy falls as 1/k², and the de Broglie wavelength grows as k. Exactly k wavelengths wrap around orbit k. The total energy is −K. When the electron drops to orbit 1 it speeds up and its kinetic energy rises, but its total energy falls by the same amount. That energy leaves as a Lyman-series photon in the ultraviolet.
Key takeaways
- Kk = (h/4π) k vk/rk = e²/(8πϵ0rk), and Ek = −Kk.
- |ΔE| = |ΔK|: the same expression, not twice it.
- λk = 2πrk/k = e²/(4ϵ0k Kk). Keep the 1/k.
- Lyman: hν = K1 − Kn = 13.6(1 − 1/n²) eV, which is ultraviolet.
Verification: an independent derivation, a sympy route, an exact numerical route with CODATA constants for every Lyman line n = 2…6, and the page's own engine, run by tests/verify_p1phyq05.py. The official key (A, C) and the MathonGo solution (A, C) agree. Status: script-verified by the PrayogX simulation factory; no review by a person has been recorded. Orbit radii are not drawn to scale (the true ratio is k²), and the ultraviolet photon is drawn violet.
How to use this simulation
- Choose the starting orbit with From orbit n (2 to 6), then press ▶ START EXPERIMENT.
- Watch the electron and its de Broglie wave on orbit n: exactly n wavelengths fit around it.
- The electron jumps to orbit 1 and emits a photon. The readouts show v, r, K and λ before and after.
- The last stage checks each option's expression against the measured change: ✓ for (A) and (C), ✗ for (B) and (D).
- Replay runs it again. Reset clears it. Classroom fills the screen for a projector.