PRAYOGX
ADV-2026-P2-CHE-Q06

Xenon fluorides: make P in the reactor, walk it to Q and R, then count the lone pairs yourself

JEE Advanced 2026 Paper 2 Chemistry Q.6 · Section 2 p-Block · Group 18 VSEPR
Answer
Run the experiment
Test all four statements on the bench to unlock.

01Original question — verbatim

Correct statement(s) about the compounds P, Q and R is(are)
Xe(g)  +  F2(g)   (1 : 5 ratio)   ——873 K, 7 bar——>  P
P  +  O2F2   ————143 K————>  Q  +  O2
Q  +  H2O   —complete hydrolysis—>  R  +  HF
  • (A)
    P has two lone pairs of electrons on the central atom.
  • (B)
    Q has a perfect octahedral geometry.
  • (C)
    Q can act as a fluorinating agent.
  • (D)
    The molecular structure of R is trigonal pyramidal.

Multiple options may be correct (+4 / partial / −1). Nothing on this page is looked up from an answer key — identify P, Q and R on the bench, then measure each claim.

02The fluorination reactor — make P

Xenon and fluorine give three different fluorides, and which one you get is decided by how much fluorine you give the xenon. Set the mixture and the conditions, then run the reactor. The paper hands you one specific recipe; find it on the map.

Nickel reactor

Xe F₂ product jiggle speed ∝ temperature · crowding ∝ pressure

Charge and conditions

: 1
0.20 to 40.0 · try 1/2, 5 or 20 — this is the control that decides the product
K
400 to 1000 K · the reaction needs heat to start at all
bar
1 to 100 bar · only the highest fluoride needs real pressure
Run

Product

the reactor makes
—
Set the mixture and press Run.
XeF₂ recipe · Xe : F₂ = 2 : 1 · 673 K · 1 bar
XeF₄ recipe · Xe : F₂ = 1 : 5 · 873 K · 7 bar
XeF₆ recipe · Xe : F₂ = 1 : 20 · 573 K · 60–70 bar
F atoms per Xe
—
supplied
Xe oxidation state
—
in the product
bond pairs
—
around Xe
lone pairs
—
around Xe

03The chain — P to Q to R

Every step is balanced atom by atom in front of you. Nothing is asserted: if the fluorine does not add up, the step will not go green.

Reaction chain

873 K, 7 bar · Xe : F₂ = 1 : 5
Xe  +  2 F2  ⟶  P
143 K · dioxygen difluoride
P  +  O2F2  ⟶  Q  +  O2
complete hydrolysis
Q  +  3 H2O  ⟶  R  +  6 HF
Make P in the reactor above, then walk the chain one step at a time.

Fluorinating assay on Q

A fluorinating agent hands fluorine to something else and is itself reduced. Offer Q a substrate and watch the xenon oxidation state.

Pick a substrate to run the assay.

04Molecule bench — count the pairs yourself

Pick a species and the bench builds it from its valence electrons: bonds first, then whatever is left over as lone pairs. Drag the model to turn it. The geometry name is derived from the counts, not typed in.

Species

Electron bookkeeping

steric number
—
bp + lp
bond pairs
—
σ to ligands
lone pairs
—
on Xe
bond angle
—
degrees

05Verdict on each statement

Commit to a prediction, then check it against what the bench measured. The verdict column is computed from your own bookkeeping — there is no stored answer key on this page.

Lab notebook

Written as you work. Only things you actually demonstrated appear here.

Nothing recorded yet — run the reactor, walk the chain and open the species on the bench.

Predict, then check

06Step-by-step solution

The solution is still locked

Test all four statements on the bench above and the derivation opens by itself.
Statements tested: 0 of 4 — open XeF₄, XeF₆ and XeO₃ on the bench and run the fluorinating assay

07Concepts and classification

Relations used

lone pairs = (valence e⁻ − bonding e⁻) / 2
steric number = bond pairs + lone pairs
Xe + F2 → XeF2 / XeF4 / XeF6 — the ratio decides
XeF4 + O2F2 → XeF6 + O2  (143 K)
XeF6 + 3H2O → XeO3 + 6HF  (complete)
XeF6 + H2O → XeOF4 + 2HF  (partial — not this question)

Classification

Simulation IDADV-2026-P2-CHE-Q06
Exam / Year / PaperJEE Advanced · 2026 · Paper 2
SubjectChemistry (Inorganic)
ChapterThe p-Block Elements (Group 18)
TopicNoble gas compounds
SubtopicsPreparation of xenon fluorides · VSEPR and steric number · Lone pairs and distorted geometries · Hydrolysis of XeF6 · Xenon fluorides as fluorinating agents · Oxidation states of xenon
Question typeMultiple correct MCQ (+4 / partial / −1)
DifficultyModerate
Answer— run the experiment